
The Kyoto Protocol calls for a reduction in emissions of chemicals that have global warming potentials (GWPs) that make them greenhouse gases (GHGs). Unfortunately, there is a lack of data for most species that are thought to be potential GHGs, and no information is available about their degradation byproducts.
Global warming potentials (GWPs) of chemicals have been measured only experimentally and exist for only a small percentage of chemicals. However, degradation products may cause additional global warming, which has been ignored in the literature because it is not feasible to study experimentally. This work will use theoretical chemistry to predict GWPs for hydrofluoroethers that are being introduced as fourth generation refrigerants and second generation replacement solvents. The data generated will be used to apply for external funding.
The grant will cover the costs to pay two undergraduate students for their hourly work, including summer support, in carrying out quantum chemical calculations and analyzing the results of the project.